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How are polyurethanes produced?

Polyurethanes are produced through a chemical reaction between two main components: an isocyanate and a polyol. This process is known as polyurethanation and can take place through various production techniques. Here is an overview of the general steps involved in the production of polyurethanes:

Material selection: The production of polyurethanes requires the selection of appropriate isocyanates and polyols according to the desired properties of the end product. The most common isocyanates used are toluene diisocyanate (TDI) and diphenylmethane diisocyanate (MDI), while the polyols can be polyesters, polyether or recycled polyurethane-based polyols.

Preparation of the components: Isocyanates and polyols are prepared separately and may undergo pre-treatment processes, such as moisture removal or chemical modification, to achieve the desired material characteristics.

Dosage of components: The isocyanates and polyols are accurately dosed according to a specific formula that determines the chemical composition of the final polyurethane. Dosing can be carried out manually or using automated dosing systems.

Chemical reaction: Isocyanates are mixed with polyols and a chemical reaction known as polyurethanation takes place. During this reaction, the isocyanates react with the hydroxyl groups of the polyols to form urethane bonds. This reaction typically takes place in the presence of catalysts, which accelerate the polymerisation process.

Modification of properties: During the production process, modifications can be made to the properties of the polyurethane by adding additives, such as blowing agents to form foams, stabilisers to improve weather resistance, dyes to impart pigmentation, flame retardants to improve fire resistance, and more.

Moulding processes: After the chemical reaction, polyurethane can undergo various moulding processes depending on the desired application. These processes may include casting, spraying, extrusion, injection moulding or lamination.

Curing and finishing: Once formed, polyurethanes must undergo a curing or hardening process to allow the material to achieve its final properties. This may require reaction time at room temperature or the use of controlled heat treatments.


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